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Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Marriott, Karla-Sue; Anderson, Mario; Jackson, Yvette A.
Author Affiliation, Ana.
Department of Chemistry
Article Title
Synthesis of a 2,3-Dimethoxyrotenonoid
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Heterocycles
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2001
Volume ID
55
Issue ID
1
Page(s)
91-98
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
Photo-Fries rearrangement of the o- fluoro ester of 3-hydroxy-6,7-dimethoxycoumarin yielded the corresponding 3-hydroxy-4-(2-fluorobenzoyl)-coumarin which, in the presence of potassium carbonate, cyclised to the 2,3-dimethoxyrotenonoid. (1)-Benzofuran-(2,3-c)–(6H, 12H)-(1)–benzoxepin-6-ones underwent oxidation to the corresponding b -rotenonoids reluctantly.....
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