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Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Bakir, Mohammed A.
Author Affiliation, Ana.
Department of Chemistry
Article Title
Fac-Tricarbonyl[hydroxybis(2-pyridyl)methanolato- kappa3N,O,N']rhenium(I)
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Acta Crystallographica
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2002
Volume ID
C58
Issue ID
Pt 2
Page(s)
m74-m76
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
The Re(I) centre in the title compound, [Re(C(11)H(9)N(2)O(2))(CO)(3)] or fac-Re(CO)(3)(dpkO,OH) [dpkO,OH is hydroxybis(2- pyridyl)methanolato], (I), is in a pseudo-octahedral environment in which the major distortion is due to the constraints associated with the tridentate binding of the dpkO,OH anion. The carbonyl groups are orthogonal, with an average C-Re-C angle of 90.2(3) degree. The molecules pack in stacks of antiparallel tapes of (I) interlocked via a network of hydrogen bonds.....
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