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Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Bakir, Mohammed A.
Author Affiliation, Ana.
Department of Chemistry
Article Title
The first pyridyl N,N'-coordinated di-2-pyridyl ketone oxime, fac- tricarbonylchloro(di-2-pyridyl ketone oxime)rhenium(I) dimethyl sulfoxide solvate
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Acta Crystallographica
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2001
Volume ID
C57
Issue ID
Pt. 10
Page(s)
1154-56
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
The structure of the first metal compound of pyridyl N,N'-coordinated di-2-pyridyl ketone oxime (dpk-o), fac-tricarbonylchloro(di-2-pyridyl- kappaN ketone oxime)rhenium(I) dimethyl sulfoxide solvate, [ReCl(C(11)H(9)N(2)O)(CO)(3)].C(2)H(6)OS, (I), is reported. The coordinated atoms (two N atoms from the pyridyl rings, three C atoms from the carbonyl groups and one Cl atom) are in a distorted octahedral arrangement, with the major distortion being due to the constraints associated with the binding of dpk-o. The packing of the molecules shows antiparallel tapes of (I), with a network of classical (O...H-O) and non-classical (O...H-C) hydrogen bonds between the dimethyl sulfoxide solvate molecule and the complexed metal moiety.....
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Keywords