View
Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Mulder, Willem H.; Dasgupta, Tara P.; Stedman Geoffrey
Author Affiliation, Ana.
Department of Chemistry
Article Title
Theoretical estimates of association constants for contact triple-ion formation
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Inorganic Reaction Mechanisms
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2000
Volume ID
1
Issue ID
n/a
Page(s)
257-64
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
A formula for the calculation of formation constants for ion-triplets in contact, KIT, is derived on the basis of a thermodynamic argument. This approach also yields an expression for the association constants for ion-pairs, KIP, within the same approximation, leading to a modification of the familiar Fuoss equation. The formula for KIT is compared with literature data for transition metal cyano complexes. (AU)....
read more