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Publication Type
Journal Article
Author, Analytic
Abdur-Rashid, Kamaluddin; Dasgupta, Tara P.; Blundell, Nicholas J.; Burgess, John; Drasdo, Duncan N.
Author Affiliation, Ana.
Department of Chemistry
Article Title
Solvation of inorganic complexes: Transfer chemical potentials for mono-and bi-nuclear cobalt (III) complexes to methanol + water mixtures
Medium Designator
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Connective Phrase
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Journal Title
Transition metal chemistry
Translated Title
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Reprint Status
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Date of Publication
2005
Volume ID
30
Issue ID
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Page(s)
176-184
Language
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Connective Phrase
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Location/URL
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ISSN
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Notes
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Abstract
Solubilities in MeOH-H2O mixtures at 298.2 K are reported for a number of salts of mono- and bi-nuclear cobalt (III) complexes. From these solubilities and published single ion transfer chemical potentials, on the TPTB (Ph4P+ = BPh-4) assumption, transfer chemical potentials have been derived for these mono- and bi-nuclear cobalt (III) complexes. The results and trends are discussed in relation to those for other complexes and ions in these binary aqueous solvent mixtures.....
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