Abdur-Rashid, Kamaluddin; Dasgupta, Tara P.; Blundell, Nicholas J.; Burgess, John; Drasdo, Duncan N.
Author Affiliation, Ana.
Department of Chemistry
Solvation of inorganic complexes: Transfer chemical potentials for mono-and bi-nuclear cobalt (III) complexes to methanol + water mixtures
Transition metal chemistry
Date of Publication
Solubilities in MeOH-H2O mixtures at 298.2 K are reported for a number of salts of mono- and bi-nuclear cobalt (III) complexes. From these solubilities and published single ion transfer chemical potentials, on the TPTB (Ph4P+ = BPh-4) assumption, transfer chemical potentials have been derived for these mono- and bi-nuclear cobalt (III) complexes. The results and trends are discussed in relation to those for other complexes and ions in these binary aqueous solvent mixtures.....