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Publication Type
Journal Article
Author, Analytic
Singh-Wilmot, Marvadeen A.; Kahwa, Ishenkumba A.; Lough, A.J.
Author Affiliation, Ana.
Department of Chemistry
Article Title
Octaaquatetrakis(mu(2)-2,6-diformyl-4-methylphenolato)tetra-mu(3)-hydroxo-tetraneodymium(III) trifluoromethanesulfonate butanol disolvate tetrahydrate
Medium Designator
n/a
Connective Phrase
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Journal Title
Acta crystallographica section E-structure reports online
Translated Title
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Reprint Status
Refereed
Date of Publication
2005
Volume ID
61
Issue ID
n/a
Page(s)
M970-M972 Part 5, MAY 2005
Language
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Connective Phrase
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Location/URL
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ISSN
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Notes
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Abstract
The title compound, [Nd-4(μ(3)-OH)(4)(μ(2)-C9H7O3)(4)(H2O)(8)]( CF3SO3)(4) • 2C(4)H(10)O • 4H(2)O, was synthesized from Nd(CF3SO3) (3) and 2,6-diformyl-4-methylphenol at relatively high pH. The cation, which lies on a crystallographic twofold axis, features a cubane-type [Ln(4)(OH)(4)](8+) core of four Nd-III cations and four μ(3)-OH ligands occupying alternate vertices of a distorted cube.....
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Keywords