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Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Richards-Johnson, Roxan U.; Kahwa, Ishenkumba A.; Lough, A.J.
Author Affiliation, Ana.
Department of Chemistry
Article Title
Aqua[N,N ',N '',N '''-tetrakis(2-hydroxyethyl)-1,4,7,10-tetrazacyclododecane-kappa N-4]neodymium(III) tris(perchlorate) 1.25-hydrate
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Acta crystallographica section E-structure reports online
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2003
Volume ID
59
Issue ID
Part 11
Page(s)
M1022-M1024
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
The asymmetric unit of the title structure, [Nd(C16H36N4O4)-(H2O)](ClO4)(3).1.25H(2)O, (I), contains two independent Nd-III cations, six perchlorate anions and two and a half solvent water molecules. Compound (I) is a product of a program exploring the formation of polynuclear metallo-nanoclusters from oligomerization of aziridineethanol in the presence of lanthanide(III) salts. Under moderately acidic or basic solutions protonation of alcoholic sites is maintained and no oligomerization via bridging alcoholic sites is found. The crystal structure contains a three-dimensional network of O-H...O hydrogen bonds.....
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Keywords