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Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Lui-Lym, J; Dasgupta, T.P; Maragh, P.T; Beckford, F; Stedman, G
Author Affiliation, Ana.
n/a
Article Title
Kinetics and mechanism of the reaction between the di--cyanobis[tetracyanoferrate(III)] complex ion and sulfite in aqueous solution
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Inorganica Chimica Acta
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2007
Volume ID
360
Issue ID
7
Page(s)
2284-2290
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
The kinetics of the stepwise reduction of the title complex [Fe2(CN)10]4- by sulfite have been studied in the presence of air as a function of pH, sulfite concentration, temperature and ionic strength using stopped-flow and conventional spectrophotometric techniques. The kobs versus pH profile shows a marked increase in rate with increase of pH over the range 3.7....
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