View
Publication Type
Journal Article
UWI Author(s)
Author, Analytic
Payne, V.C.R; Headley, O.S; Stibrany, R.T; Maragh, P.T; Dasgupta, T.P; Newton, A.M; Holder, A.A
Author Affiliation, Ana.
n/a
Article Title
The crystal structure of a bis(2,6-pyridinedicarboxylato)chromate(III) anion with an elaborate network of hydrogen bonding and stacking
Medium Designator
n/a
Connective Phrase
n/a
Journal Title
Journal of Chemical Crystallography
Translated Title
n/a
Reprint Status
Refereed
Date of Publication
2007
Volume ID
37
Issue ID
4
Page(s)
309-314
Language
n/a
Connective Phrase
n/a
Location/URL
n/a
ISSN
n/a
Notes
n/a
Abstract
The synthesis, X-ray crystallography, spectroscopic, and electrochemical properties of the title compound, [Hdpa][Cr(dipic)2]3H2O, 1, are reported. Compound 1 crystallized in the triclinic space group P-1 with a=7.1057(11) Armstrong, b=12.965(2) Armstrong, c=14.269(2) Armstrong, =80.306(3), =82.101(2), =83.799(2), and V=1278.6(4) Armstrong3 with Z=2. The distorted octahedral chromium anions are part of an elaborate network of hydrogen bonding formed by the waters of solvation, the anion, and cation as well as -stacking interactions.....
read more